rotational isomer - определение. Что такое rotational isomer
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Что (кто) такое rotational isomer - определение

TYPE OF CHEMICAL ISOMERISM
Endo conformer; Endo isomer; Exo isomer

Structural isomer         
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COMPOUND WHOSE MOLECULE HAS THE SAME NUMBER OF ATOMS OF EACH ELEMENT
Constitutional isomerism; Functional isomer; Structural Isomer; Functional isomers; Regioisomer; Structural isomers; Positional isomer; Skeletal isomer; Positional isomerism; Constitutional isomer; Structural isomerism; Constitutional isomers; Structural Isomers; Combinational isomer
In chemistry, a structural isomer (or constitutional isomer in the IUPAC nomenclature) of a compound is another compound whose molecule has the same number of atoms of each element, but with logically distinct bonds between them. The term metamer was formerly used for the same concept.
Rotational energy         
KINETIC ENERGY OF ROTATING BODY WITH MOMENT OF INERTIA AND ANGULAR VELOCITY
Angular kinetic energy; Rotational kinetic energy
Rotational energy or angular kinetic energy is kinetic energy due to the rotation of an object and is part of its total kinetic energy. Looking at rotational energy separately around an object's axis of rotation, the following dependence on the object's moment of inertia is observed:Resnick, R.
Isomerism         
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  • Molecular models of cyclohexane in boat and chair conformations.  The carbon atoms are colored amber or blue according to whether they lie above or below the mean plane of the ring. The C–C bonds on the ring are light green.
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  • O}}: '''I''' 1-propanol, '''II''' 2-propanol, '''III''' ethyl-methyl-ether.
MOLECULE WITH IDENTICAL ATOMIC COMPOSITION AS ANOTHER, BUT WITH DIFFERENT STRUCTURES OR ORIENTATIONS
Isomers; Isomeric; Isomerism; Molecular isomerism; Chemical isomer; Isomerizing; Isomerized
·noun The state, quality, or relation, of two or more isomeric substances.

Википедия

Endo-exo isomerism

In organic chemistry, endoexo isomerism is a special type of stereoisomerism found in organic compounds with a substituent on a bridged ring system. The prefix endo is reserved for the isomer with the substituent located closest, or "syn", to the longest bridge. The prefix exo is reserved for the isomer with the substituent located farthest, or "anti", to the longest bridge. Here "longest" and "shortest" refer to the number of atoms that comprise the bridge. This type of molecular geometry is found in norbornane systems such as dicyclopentadiene.

The terms endo and exo are used in a similar sense in discussions of the stereoselectivity in Diels–Alder reactions.